Electro-osmotic flow of fractional second-grade fluid with fractional Cattaneo heat flux through a vertical microchannel

This study investigates the unsteady electro-osmotic flow (EOF) of a fractional second-grade fluid through a vertical microchannel with convection heat transfer. The fractional Cattaneo heat flux model will be used to modify the heat equation. The solutions for the velocity and the temperature have been derived by employing the Laplace and finite Fourier sine transforms and their numerical inverses. The results show that at the beginning of the time period, the fractional parameter postpones the movement of the fluid. Furthermore, the results show that at the high values of retardation time (non-Newtonian case), the required time for the velocity and the flow rate to reach the steady state increases. Moreover, the heat relaxation time reduces the heat transfer until a critical time, and then the effect reverses.     

Reversible photoinduced bi-state polymer solar cells based on fullerene derivatives with azobenzene groups

[6,6]-Phenyl-C61-butyric acid-4′-hydroxyl-azobenzene ester (PCBAb) was synthesized and used as the acceptor in the fabrication of reversible UV–VIS response bi-state polymer solar cells (PSCs) based on the photoinduced cis–trans isomerization of PCBAb. The device can be switched between “active” and “sleep” by the irradiation of UV and visible light, respectively. The active device has a PCE of 2.0%. With UV irradiation, the device goes to “sleep” with a lowered PCE (0.4%), and simultaneously decreased J_sc, V_oc and FF, while after visible light treatment, the device is made “active” again. The mechanism of the bi-state process involves the different electron mobilities of the isomers.     

Synthesis and characterization of coumarin thiazole derivative 2-(2-amino-1,3-thiazol-4-yl)-3H-benzo[f]chromen-3-one with anti-microbial activity and its potential application in antimicrobial polyurethane coating

Coumarin, thiazole and their respective derivative products are some of the oldest and most commonly known class of nitrogen and sulphur containing compounds. In recent years there has been considerable interest in this coumarin–thiazole derivatives, which have been reported to exhibit significant biological activity and are widely used as pharmaceuticals. They are capable of imparting anti-microbial activity properties when incorporated into polymers and polymer composites. In this research, coumarin–thiazole derivative 2-(2-amino-1,3-thiazol-4-yl)-3H benzo[f]chromen-3-one (compound III), was prepared and its structure was confirmed by means of its spectra data. It was also screened for its anti-microbial activity against eight different micro-organisms when physically incorporated into a polyurethane varnish formula. Experimental coatings were manufactured on a laboratory scale and applied by means of a brush on both glass and steel panels. The results of the biological activity indicated that the polyurethane varnishes containing the 2-(2-amino-1,3-thiazol-4-yl)-3H-benzo[f]chromen-3-one (compound III) derivative, exhibit a very good antimicrobial effect. The molecular modeling study revealed that it is biologically safe, it is active and it fulfills Lipinski's rule of five. The physical and mechanical resistances of the polyurethane varnish formulations were also studied to evaluate any drawbacks associated with the addition of the derivative. The studies indicate that the physical incorporation of compound III actually enhances slightly both the physical and mechanical properties.     

苯胺及其衍生物的气相色谱分析方法研究

建立了气相色谱法对苯胺及其五种衍生物进行分离与同时测定的方法。最佳色谱分离条件如下:HP-5MS空心毛细管柱(30 m×0.32 mm×0.25μm);程序升温方式:初始温度70℃,以20℃/min升至150℃,保持1 min;以氮气为载气,流速为5.0 m L/min;尾吹气(氮气)流速为30 m L/min;氢气流速为35 m L/min;空气流速为400 m L/min;不分流进样,进样量为1μL;进样口温度为260℃,检测器温度为320℃。在最佳实验条件下,六种组分在4 min内全部出峰,达到较好的分离,实现对组分的分离与同时检测。     

多面体低聚倍半硅氧烷的合成研究进展

首先介绍了多面体低聚倍半硅氧烷(POSS)的结构、分类和性质,然后综述了三官能度硅烷或四官能度硅烷在酸、碱和有机盐催化下通过水解缩合反应合成POSS的研究进展,以及以POSS为母体、通过封端关笼法、闭环法和官能团转化法合成POSS的研究进展。     

Phosphorylation of Glycine Derivatives via Copper(I)‐Catalyzed Csp3−H Bond Functionalization

A simple and efficient one‐pot approach has been developed for a copper‐catalyzed phosphorylation of glycine derivatives under air and at room temperature. The present cross‐dehydrogenative coupling allows various methoxyphenyl‐protected glycine derivatives to be phosphorylated using diverse alkyl and aryl phosphites through an oxidative coupling between Csp³−H and P−H bonds catalyzed by copper iodide. This method provides a new synthetic tool to obtain biologically active α‐aminophosphonates.

     

吲哚-2-酮类衍生物的合成

以苯胺类衍生物为起始原料,先经Sandmeyer合成得到靛红类衍生物,再经水合肼还原得到系列吲哚-2-酮类衍生物:7-氯吲哚-2-酮、5-氯吲哚-2-酮、5-甲基吲哚-2-酮和5-溴吲哚-2-酮,产率分别为52.1%、49.8%、59.3%和65.2%。     

Weighting ensemble least-square method for flutter derivatives of bridge decks

In this paper, a reliable but simple identification method, here called the weighting ensemble least-square method (WELS), has been developed to extract all eight flutter derivatives of bridge deck from free vibration records. For every wind speed, free vibration test of section model is generally repeated several times in order to obtain more reliable parameter estimates. In the WELS method, many free vibration records at the same wind speed are regarded as an ensemble. The common mode parameters are then identified simultaneously from the ensemble data. The parameter fit is obtained by a nonlinear least-square method. Weighting factors are proposed to make each experiment record with the same weight in total residual error analysis. The ensemble composed of many records can reduce the effect of the colored noise of few records on the convergence of least-square iteration process. The flutter derivatives of two section models are identified to indicate the reliability and effectiveness of the WELS method.     

风雨共同作用下平板模型的气动导数试验研究

气动导数是大跨桥梁结构颤振和抖振分析中确定颤振临界风速和抖振响应的重要依据。在实际中 ,强风(特别是台风 )一般总伴随着暴雨。但遗憾的是 ,目前所有的研究均是在均匀风场或紊流风场中识别气动导数 ,而没有考虑暴雨的作用。本文采用随机系统识别方法 ,在模拟的风雨共同作用条件下识别了薄平板模型的气动导数。初步研究结果表明 ,风雨共同作用下平板结构的气动导数明显不同于仅有风作用的结果。这一新发现值得研究人员和工程技术人员的重视     

1,3-二取代环己烷衍生物的结构和旋光方向

按照螺旋理论,1,3-二取代环己烷衍生物的结构中存在的二面角螺旋旋光度代数和为零,不应具有旋光性,但是它们却是光学活性的.这是由于两个取代基的吸或供电子引起了相邻化学键的电子云密度发生变化,使旋光度相应变化,从而导致旋光性.但是,一般而言,这类化合物的旋光度都比较小.